The study of blood, the blood-forming organs, along with blood diseases and their treatment

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What percentage of human capillaries are located in the skin?

As in the subject line, what percentage of capillaries in a human (expressed in terms of total length, I suppose) are located in the skin, as opposed to internal organs? Google scholar has not turned ...
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How is a blood sample analyzed to give the different levels of metabolites?

How is a blood sample analyzed to give the different levels of metabolites? Are there any any procedural differences with each blood test? Thanks in advance!