Color perception: There are several competing/complementary theories of color perception: the most popular, trichromatic theory, being complemented by the opponent process theory. There is also Land’s Retinex theory and Goethe’s (yes, that Goethe) Theory of Colors.
According to Peter Vishton: (Teaching Company, Secrets of Human Perception)
Overall, the opponent process theory of color complements the
trichromatic theory of color. The trichromatic theory explains the
retinal receptor level, whereas the opponent process theory explains
processing in the lateral geniculate nucleus and the visual cortex
The perception of color by the human brain is an extremely complex interplay of many functions of which the frequency and intensity of light entering the eye is only one. (Do you remember The Dress) Color is an artifact manufactured by the brain. How the brain interprets color depends on, amongst other things, the ambient light, surroundings, shadow and contrast. A white table cloth appears white when illuminated by daylight, but also when illuminated by a yellow light for example a candle.
Edwin Land (of Polaroid fame) performed many experiments: Land
In one set of experiments, the illumination was adjusted so that, for example, a white area of one Mondrian sent to the eye exactly the same triplet of radiant energies as a green area of another Mondrian. The two areas continued to appear white and green. Retinex Theory
However, to answer your question from trichromatic theory:
The receptors send a series of impulse to the brain proportional to their response to the frequency and intensity of the light striking them. The brain interprets the color it sees by comparing the levels of response from the various receptors. Different relative levels are interpreted as different colors. So, from your diagram S=10%, M=0.5%, L=0.5% activation is interpreted as violet. Rods will give a measure of the total intensity of light for comparison.
If you consider the sensitivity of the different receptors to violet light, the output from these is a unique combination that is sent to the visual cortex. There is no other possible light source that will produce this array. The brain has no trouble labeling this as violet.
Blue light would send S=100%, M=10%, L=5% (This assuming log10 scale)
Adding blue light to red will give magenta - for which there is no single monochromatic color.