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As far as I know, the Marcus Theory explains the rates of electron transfers in reactions as a function of differences in free energy between the product/reactant's potential well.

Furthermore, there is the so called inverted region which is often said to be important to explain effects as the photosynthesis. Sadly, I do not see the connection here. The inverted region seems to reduce the transfer rate in the backwards reaction but not in the forwards reaction which creates a net reaction flux. But how can this be explained by the Marcus Theory? I tried to read several sources which claimed to talk about this online, but apparently missed the crucial point.

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  • $\begingroup$ Please provide a reference link to the Marcus Theory. I have never heard of it myself, and suspect that very few on this site will have. $\endgroup$ – David Mar 1 '18 at 16:45
  • $\begingroup$ @David I am tlaking about this theory: en.wikipedia.org/wiki/Marcus_theory Do you think I should rather ask this question at the chemistry stackexchange? $\endgroup$ – zimmerrol Mar 1 '18 at 16:49
  • $\begingroup$ Not sure. I'd wait a little to see if anyone answers. $\endgroup$ – David Mar 1 '18 at 17:04

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