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The differential uptake of different isotopes of carbon is covered well at:
https://en.m.wikipedia.org/wiki/Fractionation_of_carbon_isotopes_in_oxygenic_photosynthesis
Plants have a lower proportion of C-13 than atmospheric CO2.
The two mechanisms that cause this are the reduced diffusion speed of the heavier C-13, and an energetic difference in the chemical ...
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