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Added note on Pi.
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David
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Although texts such as Berg et al. tend to refer to inorganic phosphate, $\ce{P_i}$, as orthophosphate ($\ce{PO4^{3-}}$), the term inorganic phosphate is used because in aqueous solution at pH 7.6 several phosphate species exist, the predominant one being $\ce{HPO4^{2-}}$. If this is regarded as $\ce{P_i}$, then it is the source of the $\ce{H^{+}}$, and the equation balances.

Note added by David:

On checking I find, in contrast to Berg, Lehninger’s book defines $\ce{P_i}$ as monohydrogen phosphate ($\ce{HPO4^{2-}}$), and Fersht actually writes the equation of the reaction (16-1) with $\ce{HPO4^{2-}}$ rather than $\ce{P_i}$.

Although texts such as Berg et al. tend to refer to inorganic phosphate, $\ce{P_i}$, as orthophosphate ($\ce{PO4^{3-}}$), the term inorganic phosphate is used because in aqueous solution at pH 7.6 several phosphate species exist, the predominant one being $\ce{HPO4^{2-}}$. If this is regarded as $\ce{P_i}$, then it is the source of the $\ce{H^{+}}$, and the equation balances.

Although texts such as Berg et al. tend to refer to inorganic phosphate, $\ce{P_i}$, as orthophosphate ($\ce{PO4^{3-}}$), the term inorganic phosphate is used because in aqueous solution at pH 7.6 several phosphate species exist, the predominant one being $\ce{HPO4^{2-}}$. If this is regarded as $\ce{P_i}$, then it is the source of the $\ce{H^{+}}$, and the equation balances.

Note added by David:

On checking I find, in contrast to Berg, Lehninger’s book defines $\ce{P_i}$ as monohydrogen phosphate ($\ce{HPO4^{2-}}$), and Fersht actually writes the equation of the reaction (16-1) with $\ce{HPO4^{2-}}$ rather than $\ce{P_i}$.

I have replaced incorrect references to solubility by ionization and given chemical formulae with charges.
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David
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InorganicAlthough texts such as Berg et al. tend to refer to inorganic phosphate, (PO4)$\ce{P_i}$, as orthophosphate ($\ce{PO4^{3-}}$), the term inorganic phosphate is not solubleused because in wateraqueous solution at pH 7. In cells, it exists as a mixture of hydrogen phosphate (HPO4) and dihydrogen6 several phosphate (H2PO4)species exist, both much more soluable. That's where the extra H+ comes frompredominant one being $\ce{HPO4^{2-}}$. For simplicity's sake, inorganic phosphateIf this is just indicatedregarded as Pi but that doesn't give$\ce{P_i}$, then it is the exact form it takes insource of the cell$\ce{H^{+}}$, and the equation balances.

Phosphate

Inorganic phosphate (PO4) is not soluble in water. In cells, it exists as a mixture of hydrogen phosphate (HPO4) and dihydrogen phosphate (H2PO4), both much more soluable. That's where the extra H+ comes from. For simplicity's sake, inorganic phosphate is just indicated as Pi but that doesn't give the exact form it takes in the cell.

Phosphate

Although texts such as Berg et al. tend to refer to inorganic phosphate, $\ce{P_i}$, as orthophosphate ($\ce{PO4^{3-}}$), the term inorganic phosphate is used because in aqueous solution at pH 7.6 several phosphate species exist, the predominant one being $\ce{HPO4^{2-}}$. If this is regarded as $\ce{P_i}$, then it is the source of the $\ce{H^{+}}$, and the equation balances.

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anongoodnurse
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Inorganic phosphate (PO4) is not soluble in water. In cells, it exists as a mixture of hydrogen phosphate (HPO4) and dihydrogen phosphate (H2PO4), both much more soluable. That's where the extra H+ comes from. For simplicity's sake, inorganic phosphate is just indicated as Pi but that doesn't give the exact form it takes in the cell.

Phosphate